Like @nick_sherman said. The method that I’ve found the easiest for me has been to have a php file on a server that, when called, returns the current version code of the app. This number is then compared to a locally stored number. If the numbers don’t match, then the user is told to update.
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Now, since you don’t have this kind of system already set up, it means that you are out of luck for the time being. If this system doesn’t exist in the version of your app that your users currently have, then it can’t just magically appear there. This is really one of those features that has to be included since the beginning. Now your users need to update their apps to a version where you have this check and then it’ll work for all future updates.